| Week 1 | 18-Aug-2013 | Week 2 | 25-Aug-2013 | |||
| Barcelona | – | Levante | Espanyol | – | Valencia | |
| Valencia | – | Malaga | Real Betis | – | Celta Vigo | |
| Real Madrid | – | Real Betis | Granada | – | Real Madrid | |
| Sevilla | – | Atletico Madrid | Athletic Bilbao | – | Osasuna | |
| Real Sociedad | – | Getafe | Villarreal | – | Real Valladolid | |
| Real Valladolid | – | Athletic Bilbao | Getafe | – | Almeria | |
| Osasuna | – | Granada | Elche | – | Real Sociedad | |
| Celta Vigo | – | Espanyol | Atletico Madrid | – | Rayo Vallecano | |
| Almeria | – | Villarreal | Levante | – | Sevilla | |
| Rayo Vallecano | – | Elche | Malaga | – | Barcelona | |
| Week 3 | 01-Sep-2013 | Week 4 | 15-Sep-2013 | |||
| Real Madrid | – | Athletic Bilbao | Real Betis | – | Valencia | |
| Real Valladolid | – | Getafe | Granada | – | Espanyol | |
| Almeria | – | Elche | Athletic Bilbao | – | Celta Vigo | |
| Real Sociedad | – | Atletico Madrid | Villarreal | – | Real Madrid | |
| Rayo Vallecano | – | Levante | Getafe | – | Osasuna | |
| Sevilla | – | Malaga | Elche | – | Real Valladolid | |
| Valencia | – | Barcelona | Atletico Madrid | – | Almeria | |
| Espanyol | – | Real Betis | Levante | – | Real Sociedad | |
| Celta Vigo | – | Granada | Barcelona | – | Sevilla | |
| Osasuna | – | Villarreal | Malaga | – | Rayo Vallecano | |
| Week 5 | 22-Sep-2013 | Week 6 | 25-Sep-2013 | |||
| Espanyol | – | Athletic Bilbao | Getafe | – | Celta Vigo | |
| Celta Vigo | – | Villarreal | Malaga | – | Almeria | |
| Real Madrid | – | Getafe | Barcelona | – | Real Sociedad | |
| Osasuna | – | Elche | Atletico Madrid | – | Osasuna | |
| Real Betis | – | Granada | Granada | – | Valencia | |
| Real Valladolid | – | Atletico Madrid | Athletic Bilbao | – | Real Betis | |
| Almeria | – | Levante | Villarreal | – | Espanyol | |
| Real Sociedad | – | Malaga | Elche | – | Real Madrid | |
| Rayo Vallecano | – | Barcelona | Levante | – | Real Valladolid | |
| Valencia | – | Sevilla | Sevilla | – | Rayo Vallecano | |
| Week 7 | 29-Sep-2013 | Week 8 | 06-Oct-2013 | |||
| Celta Vigo | – | Elche | Getafe | – | Real Betis | |
| Granada | – | Athletic Bilbao | Atletico Madrid | – | Celta Vigo | |
| Almeria | – | Barcelona | Malaga | – | Osasuna | |
| Real Betis | – | Villarreal | Levante | – | Real Madrid | |
| Espanyol | – | Getafe | Athletic Bilbao | – | Valencia | |
| Real Madrid | – | Atletico Madrid | Villarreal | – | Granada | |
| Osasuna | – | Levante | Elche | – | Espanyol | |
| Real Valladolid | – | Malaga | Barcelona | – | Real Valladolid | |
| Real Sociedad | – | Sevilla | Sevilla | – | Almeria | |
| Valencia | – | Rayo Vallecano | Rayo Vallecano | – | Real Sociedad | |
| Week 9 | 20-Oct-2013 | Week 10 | 27-Oct-2013 | |||
| Athletic Bilbao | – | Villarreal | Villarreal | – | Valencia | |
| Granada | – | Getafe | Getafe | – | Athletic Bilbao | |
| Real Betis | – | Elche | Elche | – | Granada | |
| Espanyol | – | Atletico Madrid | Real Sociedad | – | Almeria | |
| Almeria | – | Rayo Vallecano | Barcelona | – | Real Madrid | |
| Celta Vigo | – | Levante | Atletico Madrid | – | Real Betis | |
| Real Madrid | – | Malaga | Levante | – | Espanyol | |
| Osasuna | – | Barcelona | Malaga | – | Celta Vigo | |
| Real Valladolid | – | Sevilla | Sevilla | – | Osasuna | |
| Valencia | – | Real Sociedad | Rayo Vallecano | – | Real Valladolid | |
| Week 11 | 30-Oct-2013 | Week 12 | 03-Nov-2013 | |||
| Athletic Bilbao | – | Elche | Getafe | – | Valencia | |
| Real Betis | – | Levante | Malaga | – | Real Betis | |
| Espanyol | – | Malaga | Real Sociedad | – | Osasuna | |
| Real Valladolid | – | Real Sociedad | Almeria | – | Real Valladolid | |
| Villarreal | – | Getafe | Elche | – | Villarreal | |
| Granada | – | Atletico Madrid | Atletico Madrid | – | Athletic Bilbao | |
| Celta Vigo | – | Barcelona | Levante | – | Granada | |
| Real Madrid | – | Sevilla | Barcelona | – | Espanyol | |
| Osasuna | – | Rayo Vallecano | Sevilla | – | Celta Vigo | |
| Valencia | – | Almeria | Rayo Vallecano | – | Real Madrid | |
| Week 13 | 10-Nov-2013 | Week 14 | 24-Nov-2013 | |||
| Granada | – | Malaga | Elche | – | Valencia | |
| Real Madrid | – | Real Sociedad | Malaga | – | Athletic Bilbao | |
| Osasuna | – | Almeria | Barcelona | – | Granada | |
| Valencia | – | Real Valladolid | Almeria | – | Real Madrid | |
| Getafe | – | Elche | Atletico Madrid | – | Getafe | |
| Villarreal | – | Atletico Madrid | Levante | – | Villarreal | |
| Athletic Bilbao | – | Levante | Sevilla | – | Real Betis | |
| Real Betis | – | Barcelona | Rayo Vallecano | – | Espanyol | |
| Celta Vigo | – | Rayo Vallecano | Real Sociedad | – | Celta Vigo | |
| Espanyol | – | Sevilla | Real Valladolid | – | Osasuna | |
| Week 15 | 01-Dec-2013 | Week 16 | 15-Dec-2013 | |||
| Elche | – | Atletico Madrid | Levante | – | Elche | |
| Granada | – | Sevilla | Atletico Madrid | – | Valencia | |
| Espanyol | – | Real Sociedad | Malaga | – | Getafe | |
| Real Madrid | – | Real Valladolid | Barcelona | – | Villarreal | |
| Valencia | – | Osasuna | Sevilla | – | Athletic Bilbao | |
| Getafe | – | Levante | Rayo Vallecano | – | Granada | |
| Villarreal | – | Malaga | Real Sociedad | – | Real Betis | |
| Athletic Bilbao | – | Barcelona | Almeria | – | Espanyol | |
| Real Betis | – | Rayo Vallecano | Real Valladolid | – | Celta Vigo | |
| Celta Vigo | – | Almeria | Osasuna | – | Real Madrid | |
| Week 17 | 21-Dec-2013 | Week 18 | 05-Jan-2014 | |||
| Atletico Madrid | – | Levante | Valencia | – | Levante | |
| Elche | – | Malaga | Malaga | – | Atletico Madrid | |
| Getafe | – | Barcelona | Barcelona | – | Elche | |
| Villarreal | – | Sevilla | Sevilla | – | Getafe | |
| Athletic Bilbao | – | Rayo Vallecano | Rayo Vallecano | – | Villarreal | |
| Granada | – | Real Sociedad | Real Sociedad | – | Athletic Bilbao | |
| Real Betis | – | Almeria | Almeria | – | Granada | |
| Espanyol | – | Real Valladolid | Real Valladolid | – | Real Betis | |
| Celta Vigo | – | Osasuna | Osasuna | – | Espanyol | |
| Valencia | – | Real Madrid | Real Madrid | – | Celta Vigo | |
| Week 19 | 12-Jan-2014 | Week 20 | 19-Jan-2014 | |||
| Atletico Madrid | – | Barcelona | Levante | – | Barcelona | |
| Espanyol | – | Real Madrid | Malaga | – | Valencia | |
| Getafe | – | Rayo Vallecano | Real Betis | – | Real Madrid | |
| Real Betis | – | Osasuna | Atletico Madrid | – | Sevilla | |
| Athletic Bilbao | – | Almeria | Getafe | – | Real Sociedad | |
| Elche | – | Sevilla | Athletic Bilbao | – | Real Valladolid | |
| Villarreal | – | Real Sociedad | Granada | – | Osasuna | |
| Celta Vigo | – | Valencia | Espanyol | – | Celta Vigo | |
| Levante | – | Malaga | Villarreal | – | Almeria | |
| Granada | – | Real Valladolid | Elche | – | Rayo Vallecano | |
| Week 21 | 26-Jan-2014 | Week 22 | 02-Feb-2014 | |||
| Valencia | – | Espanyol | Athletic Bilbao | – | Real Madrid | |
| Celta Vigo | – | Real Betis | Getafe | – | Real Valladolid | |
| Real Madrid | – | Granada | Elche | – | Almeria | |
| Osasuna | – | Athletic Bilbao | Atletico Madrid | – | Real Sociedad | |
| Real Valladolid | – | Villarreal | Levante | – | Rayo Vallecano | |
| Almeria | – | Getafe | Malaga | – | Sevilla | |
| Real Sociedad | – | Elche | Barcelona | – | Valencia | |
| Rayo Vallecano | – | Atletico Madrid | Real Betis | – | Espanyol | |
| Sevilla | – | Levante | Granada | – | Celta Vigo | |
| Barcelona | – | Malaga | Villarreal | – | Osasuna | |
| Week 23 | 09-Feb-2014 | Week 24 | 16-Feb-2014 | |||
| Valencia | – | Real Betis | Athletic Bilbao | – | Espanyol | |
| Espanyol | – | Granada | Villarreal | – | Celta Vigo | |
| Celta Vigo | – | Athletic Bilbao | Getafe | – | Real Madrid | |
| Real Madrid | – | Villarreal | Elche | – | Osasuna | |
| Osasuna | – | Getafe | Granada | – | Real Betis | |
| Real Valladolid | – | Elche | Atletico Madrid | – | Real Valladolid | |
| Almeria | – | Atletico Madrid | Levante | – | Almeria | |
| Real Sociedad | – | Levante | Malaga | – | Real Sociedad | |
| Sevilla | – | Barcelona | Barcelona | – | Rayo Vallecano | |
| Rayo Vallecano | – | Malaga | Sevilla | – | Valencia | |
| Week 25 | 23-Feb-2014 | Week 26 | 03-Mar-2014 | |||
| Celta Vigo | – | Getafe | Elche | – | Celta Vigo | |
| Almeria | – | Malaga | Athletic Bilbao | – | Granada | |
| Real Sociedad | – | Barcelona | Barcelona | – | Almeria | |
| Osasuna | – | Atletico Madrid | Villarreal | – | Real Betis | |
| Valencia | – | Granada | Getafe | – | Espanyol | |
| Real Betis | – | Athletic Bilbao | Atletico Madrid | – | Real Madrid | |
| Espanyol | – | Villarreal | Levante | – | Osasuna | |
| Real Madrid | – | Elche | Malaga | – | Real Valladolid | |
| Real Valladolid | – | Levante | Sevilla | – | Real Sociedad | |
| Rayo Vallecano | – | Sevilla | Rayo Vallecano | – | Valencia | |
| 25 | ||||||
| Week 27 | 10-Mar-2014 | Week 28 | 17-Mar-2014 | |||
| Real Betis | – | Getafe | Villarreal | – | Athletic Bilbao | |
| Celta Vigo | – | Atletico Madrid | Getafe | – | Granada | |
| Osasuna | – | Malaga | Elche | – | Real Betis | |
| Real Madrid | – | Levante | Atletico Madrid | – | Espanyol | |
| Valencia | – | Athletic Bilbao | Rayo Vallecano | – | Almeria | |
| Granada | – | Villarreal | Levante | – | Celta Vigo | |
| Espanyol | – | Elche | Malaga | – | Real Madrid | |
| Real Valladolid | – | Barcelona | Barcelona | – | Osasuna | |
| Almeria | – | Sevilla | Sevilla | – | Real Valladolid | |
| Real Sociedad | – | Rayo Vallecano | Real Sociedad | – | Valencia | |
| Week 29 | 23-Mar-2014 | Week 30 | 27-Mar-2014 | |||
| Valencia | – | Villarreal | Elche | – | Athletic Bilbao | |
| Athletic Bilbao | – | Getafe | Levante | – | Real Betis | |
| Granada | – | Elche | Malaga | – | Espanyol | |
| Almeria | – | Real Sociedad | Real Sociedad | – | Real Valladolid | |
| Real Madrid | – | Barcelona | Getafe | – | Villarreal | |
| Real Betis | – | Atletico Madrid | Atletico Madrid | – | Granada | |
| Espanyol | – | Levante | Barcelona | – | Celta Vigo | |
| Celta Vigo | – | Malaga | Sevilla | – | Real Madrid | |
| Osasuna | – | Sevilla | Rayo Vallecano | – | Osasuna | |
| Real Valladolid | – | Rayo Vallecano | Almeria | – | Valencia | |
| Week 31 | 30-Mar-2014 | Week 32 | 06-Apr-2014 | |||
| Valencia | – | Getafe | Malaga | – | Granada | |
| Real Betis | – | Malaga | Real Sociedad | – | Real Madrid | |
| Osasuna | – | Real Sociedad | Almeria | – | Osasuna | |
| Real Valladolid | – | Almeria | Real Valladolid | – | Valencia | |
| Villarreal | – | Elche | Elche | – | Getafe | |
| Athletic Bilbao | – | Atletico Madrid | Atletico Madrid | – | Villarreal | |
| Granada | – | Levante | Levante | – | Athletic Bilbao | |
| Espanyol | – | Barcelona | Barcelona | – | Real Betis | |
| Celta Vigo | – | Sevilla | Rayo Vallecano | – | Celta Vigo | |
| Real Madrid | – | Rayo Vallecano | Sevilla | – | Espanyol | |
| Week 33 | 13-Apr-2014 | Week 34 | 21-Apr-2014 | |||
| Valencia | – | Elche | Atletico Madrid | – | Elche | |
| Athletic Bilbao | – | Malaga | Sevilla | – | Granada | |
| Granada | – | Barcelona | Real Sociedad | – | Espanyol | |
| Real Madrid | – | Almeria | Real Valladolid | – | Real Madrid | |
| Getafe | – | Atletico Madrid | Osasuna | – | Valencia | |
| Villarreal | – | Levante | Levante | – | Getafe | |
| Real Betis | – | Sevilla | Malaga | – | Villarreal | |
| Espanyol | – | Rayo Vallecano | Barcelona | – | Athletic Bilbao | |
| Celta Vigo | – | Real Sociedad | Rayo Vallecano | – | Real Betis | |
| Osasuna | – | Real Valladolid | Almeria | – | Celta Vigo | |
| Week 35 | 27-Apr-2014 | Week 36 | 04-May-2014 | |||
| Elche | – | Levante | Levante | – | Atletico Madrid | |
| Valencia | – | Atletico Madrid | Malaga | – | Elche | |
| Getafe | – | Malaga | Barcelona | – | Getafe | |
| Villarreal | – | Barcelona | Sevilla | – | Villarreal | |
| Athletic Bilbao | – | Sevilla | Rayo Vallecano | – | Athletic Bilbao | |
| Granada | – | Rayo Vallecano | Real Sociedad | – | Granada | |
| Real Betis | – | Real Sociedad | Almeria | – | Real Betis | |
| Espanyol | – | Almeria | Real Valladolid | – | Espanyol | |
| Celta Vigo | – | Real Valladolid | Osasuna | – | Celta Vigo | |
| Real Madrid | – | Osasuna | Real Madrid | – | Valencia | |
| Week 37 | 11-May-2014 | Week 38 | 18-May-2014 | |||
| Levante | – | Valencia | Barcelona | – | Atletico Madrid | |
| Atletico Madrid | – | Malaga | Real Madrid | – | Espanyol | |
| Elche | – | Barcelona | Rayo Vallecano | – | Getafe | |
| Getafe | – | Sevilla | Osasuna | – | Real Betis | |
| Villarreal | – | Rayo Vallecano | Almeria | – | Athletic Bilbao | |
| Athletic Bilbao | – | Real Sociedad | Sevilla | – | Elche | |
| Granada | – | Almeria | Real Sociedad | – | Villarreal | |
| Real Betis | – | Real Valladolid | Valencia | – | Celta Vigo | |
| Espanyol | – | Osasuna | Malaga | – | Levante | |
| Celta Vigo | – | Real Madrid | Real Valladolid | – | Granada | |
