Los Blancos will travel directly on to Andalucia after the ongoing weather issues across Spain forced them to remain in Pamplona after their weekend 0-0 La Liga draw away at Osasuna.
Both players missed that game, with Carvajal serving a one game ban and Jovic struggling with a muscle injury.
Spanish international Carvajal has since picked up a thigh problem in training, and according to reports from Marca, both he and Jovic will now miss the trip to the Estadio Rosaleda in the coming days.
POSSIBLE REAL MADRID STARTING XI V ATHLETIC CLUB
Courtois; Vazquez, Ramos, Varane, Mendy; Valverde, Kroos, Casemiro; Vinicius, Benzema, Asensio