Barcelona will play PSG in the last 16 of the Champions League, with Real Madrid, Atletico Madrid and Sevilla also discovering their fate.
Real Madrid have been drawn against Italian side Napoli, Atletico's reward for topping their group is a clash with Bayer Leverkusen and Sevilla's first Champions League knockout game in six years is against English champions Leicester City.
Barca's have played French champions PSG six times in the previous four seasons, with the Catalans record three wins, two draws and a defeat – while Unai Emery, the current boss of the Parisians, has only defeated the Blaugrana once in 23 meetings.
Zinedine Zidane's side will continue their defence of the competition against Italian side Napoli, with Jose Callejon and Raul Albiol returning to the Bernabeu for the first time since the pair left the club in 2013.
Atletico played Bayer Leverkusen at this stage two seasons ago, with two 1-0 home victories seeing Los Rojiblancos eventually advance on penalties.
Sevilla face Premier League champions Leicester, who despite underperforming domestically won their Champions League group with four wins and a draw from their six games.
Champions League last 16 draw in full:
Manchester City v Monaco
Real Madrid v Napoli
Benfica v Borussia Dortmund
Bayern Munich v Arsenal
Porto v Juventus
Bayer Leverkusen v Atletico Madrid
Paris St-Germain v Barcelona
Sevilla v Leicester City
